Extraction of Lithium from Salt Lake Brine using N523-TBP Mixture System   总被引：1，自引：1，他引：0       下载免费PDF全文

SHI Dong  LI Li-juan  LI Jin-feng  JI Lian-min  SONG Fu-gen  PENG Xiao-wu  ZHANG Li-cheng  ZHANG Yu-ze  LI Hui-fang  SONG Xue-xue  NIE Feng  ZENG Zhong-min  LIU Zhi-qi  GUO Fan 《盐湖研究》2019,27(2):95-110

In this work,problems encountered by tri-butyl phosphate( TBP) in the industrialization of lithium extraction from salt lake brine were discussed in detail. The behavior of N,N-bi-( 2-ethylhexyl) acetamide( N523) during lithium extraction was investigated,and its disadvantages were analyzed in the view of practical application. An N523-TBP mixture extraction system was proposed to alleviate or avoid the defects that N523 and TBP met when they were used separately. The optimal composition of this mixture extraction system was determined to be 20% N523-30% TBP-50% kerosene.The effects of brine acidity,Fe/Li molarity ratio,phase ratio and chloride ion concentration on lithium extraction efficiency were discussed. The operation conditions in single-stage extraction were optimized as brine acidity = 0. 05 mol/L,Fe/Li molarity ratio = 1. 3,and phase ratio = 2. The high concentration of chloride ions in brine was beneficial for the extraction of lithium. The structure of the extracted complex was proposed as( LiFeCl_4·n N523·m TBP)·( 2-n) N523·( 2-m) TBP( m + n = 2) by chemical analysis and slope-fitting methods. The extraction thermodynamic functions were calculated preliminarily,and the results suggested that the extraction process was an exothermic( ΔH 0) and spontaneous( ΔG 0) reaction,and the degree of disorder increased( ΔS 0) during the extraction process. This work will give some guidance to the lithium industry of Qinghai in both the fundamental theory and practical application.  相似文献   

Test and analysis of reinforced concrete (RC) precast shear wall assembled using steel shear key (SSK)     

Shao-Dong Shen  Peng Pan  Qi-Song Miao  Wen-Feng Li  Run-Hua Gong 《地震工程与结构动力学》2019,48(14):1595-1612

Reinforced concrete (RC) precast shear walls are extensively applied in practical engineering, owing to their fast construction speed. However, because of the transport conditions, RC precast shear walls have to be separated into small wall segments during the factory prefabrication procedure before being assembled on site. Typically, wet-type jointing methods are adopted to link the segments, which is time-consuming and results in unreliable post-pouring area strength. To overcome this problem, the novel scheme of the steel shear key (SSK) featuring steel shear panels and combined fillet and plug welding is proposed. Three RC precast shear wall specimens with different linking strength, termed as weakened SSK wall, standard SSK wall, and strengthened SSK wall, respectively, and an integrated shear wall specimen were designed. Quasi-static cyclic loading was applied to investigate the specimens' dynamic properties. The test results suggest the prefabricated wall segments equipped with SSKs showed reliable stiffness and bearing capacity and were improved in energy dissipation ability, compared with conventional shear walls. As the shear stiffness and number of equipped SSKs increased, the specimens exhibited higher strength, but their ductility and energy dissipation were slightly decreased. Most importantly, the standard SSK wall specimen could achieve satisfactory bearing capacity and deformability and is thus recommended for precast building structures. Finite element method (FEM) models were established to validate the test results, and parametric study analysis was conducted based on the coupling ratio of the SSK walls. Finally, an appropriate coupling ratio range is recommended for practical engineering applications.  相似文献   

利用接收函数方法研究中国东北东南部地区不同构造体的地壳特征   总被引：3，自引：0，他引：3       下载免费PDF全文

李天觉  陈棋福 《地球物理学报》2019,62(8):2899-2917

基于我们布设的探测深俯冲的中国东北地震台阵NECsaids台阵和固定地震台长时段的观测记录及NECESSArray流动台阵共计152个台站数据提取得到的33752条P波接收函数，采用H-κ叠加分析和共转换点（CCP）叠加成像等方法进行统一分析处理，并汇集他人接收函数研究结果得到中国东北东南部地区迄今为止最高分辨率的地壳厚度和平均波速比分布图像.对中国东北东南部地区不同构造体的地壳特征综合分析研究表明：研究区不同陆块的地壳属性存在明显差别，张广才岭地块中南部的地壳厚度和波速比与华北克拉通东北缘相当，地壳厚度同地表地形之间显示有明显的正相关关系；松辽地块东南缘地壳最薄、波速比最高，地壳厚度同壳内波速比之间显示出明显的负相关关系；兴凯地块西部地区的地壳结构表现为稍厚的地壳厚度和研究区内最低的壳内波速比，其地壳厚度同壳内波速比之间亦显示出明显的负相关关系；佳木斯地块西南缘在具有"正常"的壳内波速比同时地壳最厚.研究区内的郯庐断裂带北延段在切穿其下Moho面的同时表现出南北分段的特征：北段（44.4°N—47°N）两分支之下的Moho面整体下凹，而南段（41.5°N—43.3°N）两分支之下的Moho面则整体上隆.长白山天池火山下方表现为Moho面下凹沉落及高壳内波速比特征，推测其壳内岩浆囊很可能存在于火山口东北隅至少10 km的范围内.  相似文献   

伏牛山地区森林生态系统服务权衡/协同效应多尺度分析   总被引：3，自引：0，他引：3  

张静静  朱文博  朱连奇  李艳红 《地理学报》2020,75(5):975-988

森林生态系统服务权衡与协同研究已成为当前相关学科的研究热点和前沿,对服务权衡与协同关系的多尺度分析有助于更加有效地实施森林资源管理。综合森林类型图、NDVI、气象和土壤等多源数据,借助CASA模型、InVEST 3.2模型和ArcGIS 10.2软件,开展伏牛山地区森林生态系统服务评估,运用空间叠置方法从多个空间尺度（区域、南北坡、垂直带）探讨服务权衡与协同效应。结果表明：① 研究区森林生态系统平均蓄积量为49.26 m ³/hm ²,碳密度为156.94 t/hm ²,供水深度为494.46 mm,土壤保持量为955.4 t/hm ²,生境质量指数为0.79。② 区域尺度上,28.79%的森林服务之间存在高协同效应,10.15%的森林存在低协同效应,61.06%的森林存在强权衡和弱权衡效应。③ 南北坡尺度上,南坡服务之间的协同关系优于北坡。垂直带尺度上,南坡中山落叶阔叶林带（SIII）服务之间协同关系最好,北坡低山落叶阔叶林带（NI）协同关系最差。  相似文献   

多通道瞬变电磁法频率域比值算法及视电阻率计算研究          下载免费PDF全文

张文伟  真齐辉  底青云 《地球物理学报》2018,61(10):4171-4181

视电阻率在电磁法勘探中起重要作用，可以作为初步解释结果，多通道瞬变电磁法通过大地脉冲响应的峰值时刻定义视电阻率.鉴于传统方法计算峰值时刻视电阻率需要恢复完整大地脉冲响应，本文通过研究大地脉冲响应及其频谱特征，提出一种新的频率域比值法.利用参考谱及其与一般谱的伸缩因子计算一般谱的峰值时刻，进而得到视电阻率.该方法只需大地脉冲响应单个频点幅度谱，从而不用估计整个大地脉冲响应.实际计算时，可以用大地脉冲响应多个频点幅度谱得到平均视电阻率.模拟数据与实测数据结果表明，在一维介质中，频率域比值法可以得到合理的视电阻率.  相似文献   

Mediating stream baseflow response to climate change: The role of basin storage          下载免费PDF全文

James M. Buttle 《水文研究》2018,32(3):363-378

Inter‐basin differences in streamflow response to changes in regional hydroclimatology may reflect variations in storage characteristics that control the retention and release of water inputs. These aspects of storage could mediate a basin's sensitivity to climate change. The hypothesis that temporal trends in stream baseflow exhibit a more muted reaction to changes in precipitation and evapotranspiration for basins with greater storage was tested on the Oak Ridges Moraine (ORM) in Southern Ontario, Canada. Long‐term (>25 years) baseflow trends for 16 basins were compared to corresponding trends in precipitation amount and type and in potential evapotranspiration as well as shorter trends in groundwater levels for monitoring wells on the ORM. Inter‐basin differences in storage properties were characterized using physiographic, hydrogeologic, land use/land cover, and streamflow metrics. The latter included the slope of the basin's flow duration curve and basin dynamic storage. Most basins showed temporal increases in baseflow, consistent with limited evidence of increases and decreases in regional precipitation and snowfall: precipitation ratio, respectively, and recent increases in groundwater recharge along the crest of the ORM. Baseflow trend magnitude was uncorrelated to basin physiographic, hydrogeologic, land use/land cover, or flow duration curve characteristics. However, it was positively related to a basin's dynamic storage, particularly for basins with limited coverage of open water and wetlands. The dynamic storage approach assumes that a basin behaves as a first‐order dynamical system, and extensive open water and wetland areas in a basin may invalidate this assumption. Previous work suggested that smaller dynamic storage was linked to greater damping of temporal variations in water inputs and reduced interannual variability in streamflow regime. Storage and release of water inputs to a basin may assist in mediating baseflow response to temporal changes in regional hydroclimatology and may partly account for inter‐basin differences in that response. Such storage characteristics should be considered when forecasting the impacts of climate change on regional streamflow.  相似文献   

Establishment and application of an intelligent treating method for oil spill identification     

TAN Liju  ZHAO Ruxiang  YIN Xiaonan  ZHANG Haijiang  WANG Jiangtao 《海洋学报(英文版)》2018,37(11):116-122

In the identifying process of an oil spill accident, manual integral and artificial visual comparison are commonly used at present to determine the oil spill sources, these methods are time-consuming and easily affected by human factors. Therefore, it is difficult to achieve the purpose of rapid identification of an oil spill accident. In this paper, an intelligent method of automatic recognition, integration and calculation of diagnostic ratio of Gas Chromatography-Mass Spectrometer (GC/MS) spectrum are established. Firstly, four hundreds of samples collected around the world were analyzed using a standard method and Retention time locking technology (RTL) was applied to reduce the change of retention time of GC/MS spectrum. Secondly, the automatic identification, integration of n-alkanes, biomarker compounds, polycyclic aromatic hydrocarbons and calculation of the diagnostic ratios were realized by MATLAB software. Finally, a database of oil fingerprints were established and applied successfully in a spill oil accident. Based on the new method and database, we could acquire the diagnostic ratios of an oil sample and find out the suspected oil within a few minutes. This method and database can improve the efficiency in spilled oil identification.  相似文献   

Global Statistical Assessment and Cross-Calibration with Jason-2 for Reprocessed HY-2 A Altimeter Data     

Maofei Jiang  Ke Xu  Yalong Liu 《Marine Geodesy》2018,41(3):289-312

HY-2 A (Haiyang-2 A) satellite was launched on August 16, 2011 and radar altimeter is one of its main payloads. We reprocessed two years of HY-2 A altimeter sensor geophysical dataset records (SGDR) data. This paper presents the main results in terms of reprocessed HY-2 A altimeter data quality: verification of data availability and validity, monitoring several relevant altimeter parameters, and assessment of the HY-2 A altimeter system performances. A cross-calibration analysis of reprocessed HY-2 A altimeter data with Jason-2 was conducted. The reprocessed HY-2 A altimeter data show good quality and have a low level of noise with respect to Jason-2. The same geophysical correction methods were used to calculate the sea surface height (SSH) for the two missions. The mean standard deviations of the crossover differences for HY-2 A and Jason-2 are 5.24 cm and 5.34 cm, respectively. The mean standard deviation of the crossover differences between HY-2 A and Jason-2 is 5.37 cm. These show that HY-2 A can provide SSH measurements at almost the same level of accuracy as Jason-2. The relative SSH bias between HY-2 A and Jason-2 due to the Ultra Stable Oscillator (USO) drift is obviously observed, and it can affect the calculation of mean sea level and should be further studied and corrected.  相似文献   

岛屿海岸线自动化提取及其时空变迁研究——以大连市獐子岛为例   总被引：1，自引：1，他引：0  

丁小松  单秀娟  陈云龙  金显仕  杨涛 《海洋科学》2018,42(2):46-55

海岸带是受人类活动和全球海平面上升影响的敏感地带,海岸线的提取和监测是海岸带生态系统研究和社会管理的重要内容。本文在遥感和地理信息系统的支持下,以修正的归一化水体指数(Modified Normalized Difference Water Index,MNDWI)为基础,结合遥感影像处理和直方图均衡化等技术,实现了大连市獐子岛1985—2016年海岸线的自动化提取。结果表明:(1)通过与三位专家目视解译的成果比对,本文提取海岸线的精度能满足后续研究的要求(相对误差分别为0.045%,0.032%和0.023%);(2)近30年来,獐子岛海岸线总体呈现蚀退趋势,岸线长度与岛屿面积分别呈现变短和变小的趋势,獐子岛(主岛)和大耗岛的岸线蚀退速率最大,褡裢岛次之,小耗岛最小;在人类活动较为密集的区域,海岸线呈现出较为强烈的增长趋势,海水养殖和圈海建坝是岸线增长的主要驱动力;(3)獐子岛海岸线具有显著的分形性质,分形维数随时间呈现增大的趋势,獐子岛(主岛)的分形维数最大,褡裢岛的分形维数最小。  相似文献   

黄土河谷场地地形放大效应的研究     

王良  卢育霞  马林伟  孔德政 《大地测量与地球动力学》2018,38(2):167-171

使用黄土河谷场地模型对地震动峰值加速度和频谱特征进行研究。结果表明，不同工况下各观测点PGA的放大比呈现出不同的变化规律。分析山顶和山谷各点的傅里叶谱以及谱比发现，在地形和土层共同作用下的放大效应是各自单独作用下放大效应的乘积。  相似文献